Molecular hydrogen formation on interstellar PAHs through Eley-Rideal abstraction reactions
نویسندگان
چکیده
منابع مشابه
Dynamic nitroxyl formation in the ammonia oxidation on platinum via Eley-Rideal reactions.
For over 90 years, nitroxyl (HNO) has been postulated to be an important reaction intermediate in the catalytic oxidation of ammonia to NO and its by-products (N2, N2O), but never proven to form or exist on catalytic surfaces. Here we show evidence from reactive ion beam experiments that HNO can form directly on the surface of polycrystalline Pt exposed to NH3via Eley-Rideal abstraction reactio...
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Eley-Rideal reaction mechanism is studied over rough surface of random deposition model. Two types of rough surface are considered: (1) different rough surface with same surface density and (2) different rough surface with different surface density. Dynamic scaling theory, which is generally applied to the growing surface, is applied for this reaction mechanism to obtain the temporal and spatia...
متن کاملDynamic Deuterium Enrichment in Cometary Water via Eley–rideal Reactions
The deuterium-to-hydrogen ratio (D/H) in water found in the coma of Jupiter family comet (JFC) 67P/ Churyumov–Gerasimenko was reported to be (5.3±0.7)×10, the highest among comets and three times the value for other JFCs with an ocean-like ratio. This discrepancy suggests the diverse origins of JFCs and clouds the issue of the origin of Earth’s oceanic water. Here we demonstrate that Eley–R...
متن کاملKinematics of Eley-Rideal Reactions at Hyperthermal Energies.
Direct or Eley-Rideal reactions between energetic N^{+} and O^{+} projectiles and O atoms, adsorbed onto Pt and Pd surfaces, are studied experimentally at incidence energies between 20 and 200 eV. The exit energies of the diatomic molecular products NO and O_{2} depend linearly on the incidence energy of the corresponding projectiles. A reaction mechanism is proposed, where the incident project...
متن کاملDirect Hydrogenation of Dinitrogen and Dioxygen via Eley-Rideal Reactions.
Most Eley-Rideal abstraction reactions involve an energetic gas-phase atom reacting directly with a surface adsorbate to form a molecular product. Molecular projectiles are generally less reactive, may dissociate upon collision with the surface, and thus more difficult to prove that they can participate intact in abstraction reactions. Here we provide experimental evidence for direct reactions ...
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ژورنال
عنوان ژورنال: Monthly Notices of the Royal Astronomical Society
سال: 2018
ISSN: 0035-8711,1365-2966
DOI: 10.1093/mnras/sty1528